Opal is an amorphous form of silica related to quartz, a mineraloid form, not a mineral. 3% to 21% of the total weight is water, but the content is usually between 6% to 10%. It is deposited at a relatively low temperature and may occur in the fissures of almost any kind of rock, being most commonly found with limonite, sandstone, rhyolite, marl and basalt. Opal is the national gemstone of Australia, which produces 97% of the world's supply.
 |
| An opal bracelet. The stone size is 18 by 15 mm (0.7 by 0.6 in) |
Opal's internal structure makes it diffract light; depending on the conditions in which it formed it can take on many colors. Opal ranges from clear through white, gray, red, orange, yellow, green, blue, magenta, rose, pink, slate, olive, brown, and black. Of these hues, the reds against black are the most rare, whereas white and greens are the most common. It varies in optical density from opaque to semi-transparent. For gemstone use, its natural color is often enhanced by placing thin layers of opal on a darker underlying stone, like basalt.
Precious opal
The veins of opal displaying the play of color are often quite thin, and this has given rise to unusual methods of preparing the stone as a gem. An opal is a thin layer of opal, backed by a swart mineral such as ironstone, basalt, or obsidian. The darker backing emphasizes the play of color, and results in a more attractive display than a lighter potch.
 |
| Opals can express every color in the visible spectrum. |
Precious opal shows a variable interplay of internal colors and even though it is a mineraloid, it does have an internal structure. At micro scales precious opal is composed of silica spheres some 150 to 300 nm in diameter in a hexagonal or cubic close-packed lattice. These ordered silica spheres produce the internal colors by causing the interference and diffraction of light passing through the microstructure of the opal. It is the regularity of the sizes and the packing of these spheres that determines the quality of precious opal. Where the distance between the regularly packed planes of spheres is approximately half the wavelength of a component of visible light, the light of that wavelength may be subject to diffraction from the grating created by the stacked planes. The spacing between the planes and the orientation of planes with respect to the incident light determines the colors observed. The process can be described by Bragg's Law of diffraction.
Combined with modern techniques of polishing, doublet opal produces similar effect of black or boulder opals at a mere fraction of the price. Doublet opal also has the added benefit of having genuine opal as the top visible and touchable layer, unlike triplet opals.
The triplet-cut opal backs the colored material with a dark backing, and then has a domed cap of clear quartz or plastic on top, which takes a high polish and acts as a protective layer for the opal. The top layer also acts as a magnifier, to emphasize the play of color of the opal beneath, which is often of lower quality. Triplet opals therefore have a more artificial appearance, and are not classed as precious opal.
Common opal
Besides the gemstone varieties that show a play of color, there are other kinds of common opal such as the milk opal, milky bluish to greenish (which can sometimes be of gemstone quality); resin opal, which is honey-yellow with a resinous luster; wood opal, which is caused by the replacement of the organic material in wood with opal; menilite, which is brown or grey; hyalite, a colorless glass-clear opal sometimes called Muller's Glass; geyserite, also called siliceous sinter, deposited around hot springs or geysers; and diatomite or diatomaceous earth, the accumulations of diatom shells or tests.
Other varieties of opal
Girasols, more commonly called fire opals, are transparent to translucent opals with warm body colors of yellow, orange, orange-yellow or red. They do not usually show any play of color, although occasionally a stone will exhibit bright green flashes. The most famous source of fire opals is the state of Querétaro in Mexico; these opals are commonly called Mexican fire opals. Fire opals that do not show play of color are sometimes referred to as jelly opals.
Peruvian opal (also called blue opal) is a semi-opaque to opaque blue-green stone found in Peru which is often cut to include the matrix in the more opaque stones. It does not display pleochroism.
Sources of opal
The town of Coober Pedy in South Australia is a major source of opal. The world's largest and most valuable gem opal "Olympic Australis" was found in August 1956 at the "Eight Mile" opal field in Coober Pedy. It weighs 17,000 carats (3450 grams) and is 11 inches (280 mm) long, with a height of 43⁄4 inches (120 mm) and a width of 41⁄2 inches (110 mm). It is valued at AUD$2,500,000 Australia produces around 97% of the world's opal. 90% is called 'light opal' or white and crystal opal. White makes up 60% of the opal productions but cannot be found in all of the opal fields. Crystal opal or pure hydrated silica makes up 30% of the opal produced, 8% is black and only 2% is boulder opal.
The Mintabie Opal Field located approximately 250 km north west of Coober Pedy has also produced large quantities of Crystal opal and also the rarer black opal. Over the years it has been sold overseas incorrectly as Coober Pedy Opal. The black opal is said to be some of the best examples found in Australia.
Andamooka in South Australia is also a major producer of matrix opal, crystal opal, and black opal. Another Australian town, Lightning Ridge in New South Wales, is the main source of black opal, opal containing a predominantly dark background (dark-gray to blue-black displaying the play of color). Boulder opal consists of concretions and fracture fillings in a dark siliceous ironstone matrix. It is found sporadically in western Queensland, from Kynuna in the north, to Yowah and Koroit in the south. The rarest type of Australian opal is "pipe" opal, closely related to boulder opal, which forms in sandstone with some iron-ore content, usually as fossilized tree roots. Its largest quantities are found around Jundah in South West Queensland. Australia also has opalised fossil remains, including dinosaur bones in New South Wales, and marine creatures in South Australia.
The Virgin Valley opal fields of Humboldt County in northern Nevada produce a wide variety of precious black, crystal, white, fire, and lemon opal. The black fire opal is the official gemstone of Nevada. Most of the precious opal is partial wood replacement. Miocene age opalised teeth, bones, fish, and a snake head have been found. Some of the opal has high water content and may desiccate and crack when dried. The largest black opal in the Smithsonian Institution comes from the Royal Peacock opal mine in the Virgin Valley.
Another source of white base opal or creamy opal in the United States is Spencer, Idaho. A high percentage of the opal found there occurs in thin layers.
Other significant deposits of precious opal around the world can be found in the Czech Republic, Slovakia, Hungary, Turkey, Indonesia, Brazil (in Pedro II, Piauí), Honduras, Guatemala, Nicaragua and Ethiopia.
Synthetic opal
As well as occurring naturally, opals of all varieties have been synthesized experimentally and commercially. The discovery of the ordered sphere structure of precious opal led to its synthesis by Pierre Gilson in 1974. The resulting material is distinguishable from natural opal by its regularity; under magnification, the patches of color are seen to be arranged in a "lizard skin" or "chicken wire" pattern. Furthermore, synthetic opals do not fluoresce under UV light. Synthetics are also generally lower in density and are often highly porous.
Two notable producers of synthetic opal are the companies Kyocera and Inamori of Japan. Most so-called synthetics, however, are more correctly termed "imitation opal", as they contain substances not found in natural opal (e.g., plastic stabilizers). The imitation opals seen in vintage jewelry are often foiled glass, glass-based "Slocum stone", or later plastic materials.
Other research in macroporous structures have yielded highly ordered materials that have similar optical properties to opals and have been used in cosmetics.
Local atomic structure of opals
The lattice of spheres of opal that cause the interference with light are several hundred times larger than the fundamental structure of crystalline silica. As amineraloid, there is no unit cell that describes the structure of opal. Nevertheless, opals can be roughly divided into those that show no signs of crystalline order and those that show signs of the beginning of crystalline order, commonly termed cryptocrystalline or microcrystalline opal. Dehydration experiments and infrared spectroscopy have shown that most of the H2O in the formula of SiO2·nH2O of opals is present in the familiar form of clusters of molecular water. Isolated water molecules, and silanols, structures such as Si-O-H, generally form a lesser proportion of the total and can reside near the surface or in defects inside the opal.
The structure of low-pressure polymorphs of anhydrous silica consist of frameworks of fully corner bonded tetrahedra of SiO4. The higher temperature polymorphs of silica cristobalite and tridymite are frequently the first to crystallize from amorphous anhydrous silica, and the local structures of microcrystalline opals also appear to be closer to that of cristobalite and tridymite than to quartz. The structures of tridymite and cristobalite are closely related and can be described as hexagonal and cubic close-packed layers. It is therefore possible to have intermediate structures in which the layers are not regularly stacked.
Microcrystalline opal
 |
| The crystal structure of crystalline α-cristobalite. Locally, the structures of some opals, opal-C, are similar to this. |
Opal-CT has been interpreted as consisting of clusters of stacking of cristobalite and tridymite over very short length scales. The spheres of opal in opal-CT are themselves made up of tiny microcrystalline blades of cristobalite and tridymite. Opal-CT has occasionally been further subdivided in the literature. Water content may be as high as 10 wt%. Lussatite is a synonym. Opal-C, also called Lussatine, is interpreted as consisting of localized order of α-cristobalite with a lot of stacking disorder. Typical water content is about 1.5wt%.
Non-crystalline opal
Two broad categories of non-crystalline opals, sometimes just referred to as "opal-A", have been proposed. The first of these is opal-AG consisting of aggregated spheres of silica, with water filling the space in between. Precious opal and potch opal are generally varieties of this, the difference being in the regularity of the sizes of the spheres and their packing. The second "opal-A" is opal-AN or water-containing amorphous silica-glass. Hyalite is another name for this.
Non-crystalline silica in siliceous sediments is reported to gradually transform to opal-CT and then opal-C as a result of diagenesis, due to the increasing overburden pressure in sedimentary rocks, as some of the stacking disorder is removed.